Nanoscale chemistry at interfaces

My work has focused on fundamental research concerning the interaction of the surfaces of nanomaterials with the surrounding environment.

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Improving charge transfer in CdTe solar cells

Transparent Ohmic contacts were deposited onto the CdTe absorber layer to enhance hole-extraction at the ITO/CdTe interface.

Read more at ACS Energy Letters

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Tracking oxidation of selenolate and tellurolate ligands on noble-metal nanoparticles

Selenolate and tellurolate ligands could expand our ability to tune the properties of metal nanoparticles, but their stability when bound is unknown. I have been studying how the surface of these novel nanoparticles evolves under ambient conditions following their synthesis.

Read more at Chemistry of Materials

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Probing asymmetries in the electronic properties of small noble-metal nanoparticles

Particles less than 5nm in size are assumed to be "spheroidal," but small differences in morphology can have a great impact on their effectiveness in catalysis and other applications. I have worked to demonstrate how electron spin resonance is a useful tool for exploring this asymmetry.

Read more at ACS Nano